Laplace's and Poisson's equations govern the electric potential. Their solutions via separation of variables and the method of images are the central technical tools of classical electrostatics.
PrerequisitesElectricfields(Ch.13)⋅Maxwell′sequations(Ch.M)⋅Partialdifferentialequations⋅ Fourier series
Apply separation of variables in Cartesian coordinates to solve Laplace's equation with given boundary conditions.
Expand the solution in spherical coordinates using Legendre polynomials and match boundary conditions.
Use the method of images to find the potential and surface charge for a charge above a grounded conductor.
Construct the multipole expansion and identify the leading term for a neutral charge distribution.
ES.1 Poisson's and Laplace's Equations
From Gauss's law (∇·E = ρ/ε₀) and E = −∇V, the electric potential V satisfies Poisson's equation:
∇2V=−ρ/ε0(Poisson)(ES.1)
In charge-free regions (ρ = 0), this reduces to Laplace's equation:
∇2V=0(Laplace)(ES.2)
Solutions to Laplace's equation are called harmonic functions. They satisfy the mean value theorem: the value at any point equals the average over any sphere centered there. Consequence: harmonic functions have no local maxima or minima in a charge-free region — the potential maximum is always on the boundary.
Theorem ES.1 — Uniqueness Theorem
A solution to Laplace'sequationwithspecifiedboundaryconditionsisunique.Specifically:iftwosolutionsV1²V=0inaregionandagreeonallboundaries,thenV1=V2everywhereinside.Proof:letU=V1−V2,whichsatisfies∇2U=0andU=0onboundaries.Bythemeanvaluetheorem,Uhasnointeriorextremum→U=0everywhere.■Thistheoremjustifiesthemethodofimages if you find any solution satisfying both Laplace's equation and the boundary conditions — by any method, however clever — it must be the correct solution.
ES.2 Separation of Variables
In Cartesian coordinates, try V(x,y,z) = X(x)Y(y)Z(z). Laplace's equation becomes:
X′′/X+Y′′/Y+Z′′/Z=0(ES.3)
Each term must be a constant (separation constants). For boundary conditions that demand oscillatory behavior in x and y but exponential in z, choose: X'' = −k²X, Y'' = −l²Y, Z'' = (k²+l²)Z. The general solution is built from products of sines/cosines and exponentials. Boundary conditions then fix the allowed k, l and the coefficients (via Fourier series on the boundary).
For azimuthal symmetry (V independent of φ), the separated solutions are:
V(r,θ)=∑(l=0to∞)(Alrl+Blr−l−1)Pl(cosθ)(ES.5)
where Pₗ(cos θ) are Legendre polynomials: P₀ = 1, P₁ = cos θ, P₂ = ½(3cos²θ−1), P₃ = ½(5cos³θ−3cosθ), ... The rˡ term is regular at the origin; r^(−l−1) is regular at infinity (multipole fields). A pure r^(−l−1) term with Pₗ is called a 2ˡ-pole: l=0 monopole, l=1 dipole, l=2 quadrupole.
Example ES.2 — Conducting Sphere in a Uniform Field
Interpretation:Thertermistheappliedfield;theR3/r2termisaninduceddipolewithmomentp=4πε0E0R3.Nearthesphere(atr=R):Er=−\partialV/\partialr=3E0cosθ—thefieldisthreetimestheapplied value at the poles.
ES.4 The Method of Images
The method of images uses the uniqueness theorem to find potentials near conductors: replace the conductor with fictitious image charges placed so that the boundary condition (V = 0 on conductor surface) is satisfied.
Example ES.3 — Point Charge Above a Grounded Plane
3.A charge q is placed between two parallel grounded conducting planes separated by distance d. Set up the method of images (infinite series). How does this connect to electrostatic energy in ionic crystals?
Intermediate
4.Derive the multipole expansion for the potential of a localized charge distribution. Find the leading terms for a neutral system and an electric dipole. What is the practical importance for intermolecular forces?